London Chemicals & Resources Ltd (LCR) is a Sodium Molybdate supplier and a international distributor, stockist and supplier of industrial inorganic chemicals. As one of the leading chemical catalyst companies, our business encompasses a range of metallurgical and chemical raw materials, by-products, residues and spent catalysts for downstream use, reclamation and recycling. LCR creates elegant recycling loops – buying back fully processed chemicals and metals from companies we have supplied with secondaries. These are resold to industry worldwide to restart the loop.
We are regularly purchasing and recycling secondaries containing cobalt, copper, molybdenum, nickel, tungsten, vanadium and zinc found typically in boiler ashes and slags, catalysts spent – unused or out of date, drosses, dusts, filter cakes, furnace dust, galvanic solution residues, grindings and grinding sludges, metallics, shavings, metal powders, picking solutions, plating sludges, production wastes, residues, skimmings, sludges, wastewater treatment residues.
A Useful Source
Sodium molybdate, Na2MoO4, is useful as a source of molybdenum. It is often found as the dihydrate, Na2MoO4·2H2O.
The molybdate(VI) anion is tetrahedral. Two sodium cations coordinate with every one anion.
Sodium molybdate was first synthesized by the method of hydration. A more convenient synthesis is done by dissolving MoO3 in sodium hydroxide at 50–70 °C and crystallizing the filtered product. The anhydrous salt is prepared by heating to 100 °C.
- MoO3 + 2NaOH + H2O → Na2MoO4·2H2O
The agriculture industry uses 1 million pounds per year as a fertilizer. In particular, its use has been suggested for treatment of whiptail in broccoli and cauliflower in molybdenum-deficient soils. However, care must be taken because at a level of 0.3 ppm sodium molybdate can cause copper deficiencies in animals, particularly cattle.
It is used in industry for corrosion inhibition, as it is a non-oxidizing anodic inhibitor. The addition of sodium molybdate significantly reduces the nitrite requirement of fluids inhibited with nitrite-amine, and improves the corrosion protection of carboxylate salt fluids.
In industrial water treatment applications where galvanic corrosion is a potential due to bimetallic construction, the application of sodium molybdate is preferred over sodium nitrite. Sodium molybdate has the advantage in that the dosing of lower ppm’s of molybdate allow for lower conductivity of the circulating water. Sodium molybdate at levels of 50-100 ppm offers the same levels of corrosion inhibition that sodium nitrite at levels of 800+ ppm. By utilizing lower concentrations of sodium molybdate, conductivity is kept at a minimum and thus galvanic corrosion potentials are decreased.
When reacted with sodium borohydride, molybdenum is reduced to lower valent molybdenum(IV) oxide:
- Na2MoO4 + NaBH4 + 2H2O → NaBO2 + MoO2 + 2NaOH + 3H2
Sodium molybdate reacts with the acids of dithiophosphates:
- Na2MoO4 + (R = Me, Et)(RO)2PS2H → [MoO2(S2P(OR)2)2]
which further reacts to form [MoO3(S2P(OR)2)4].
Sodium molybdate is incompatible with alkali metals, most common metals and oxidizing agents. It will explode on contact with molten magnesium. It will violently react with interhalogens (e.g., bromine pentafluoride; chlorine trifluoride). Its reaction with hot sodium, potassium or lithium is incandescent.
We can help to supply:
- Ammonium Metavanadate
- Potassium Metavanadate
- Potassium Orthovanadate
- Vanadium Pentoxide Powder
- Vanadyl Sulphate
Essential to a number of industries, Vanadium pentoxide powder and Vanadium has played a pivotal role in helping to advance the power generation whilst also helping to protect the environment by enhancing fuel economy and reducing emissions.
Because Vanadium strengthened steel is lightweight and offers increased durability, it is ideal for use in infrastructure and transportation systems.
Working Across The Globe
London Chemicals & Resources Ltd (LCR) is an international distributor, stockist and supplier of industrial inorganic chemicals. We hold several agencies and serve a global customer base both directly and via a network of local agents. LCR is committed to providing efficient service and competitive pricing to all customers.
Working closely with several producer principals around the world, quality, consistency and reliability are all important watchwords for LCR ensuring that our customers return again and again.
Raw materials are supplied for a wide range of applications including the battery, catalyst, ceramic, fertiliser, glass, plating, refinery, superalloy and other industries. Our materials are usually packed in drums or bags in accordance with UN, CLP and other applicable local and international regulations.
We deliver to our customers in quantities ranging from single bags or drums to thousands of tonnes. Transportation by air, sea, rail and truck can be arranged and all deliveries are made according to latest INCOTERMS.
Our experienced, friendly and knowledgeable staff at LCR are familiar with relevant legislation, transport procedures and documentation including REACH, SDSs and ADR.
To view our safety data sheet relating to vanadium pentoxide powder, please click here.
Who Are We?
London Chemicals & Resources Ltd (LCR) operates globally, processing non-ferrous metal-containing secondaries and distributing a range of metal salts and alloys which, in many cases, are recycled from these secondaries.
We hold exclusive agencies from Full Yield Industry Co Limited based in Taiwan and AGR-CR based in Spain. LCR source more than 90% of the spent catalysts and other feedstocks processed at Full Yield and represent them exclusively for sales of vanadium, molybdenum and nickel chemicals.
We also represent a completely new processing plant; AGR-CR treating spent catalysts and other secondaries and scheduled to start commercial operations in Q1, 2020. LCR offers commercially competitive recycling options with an emphasis on environmentally sound management. Our experienced, friendly and knowledgeable staff are familiar with relevant legislation, transport procedures and documentation including trans-frontier notifications; REACH, SDSs and ADR. Quality, consistency and reliability are all important watchwords for LCR ensuring that our customers return again and again.
For more about our services, please click here.
How Did We Do?
It is our constant goal to offer the best possible service to our clients at all times. If we have worked with you at any point in the past, please take a moment to visit the Google Maps listing below and share your experience with us.
If you would like to speak to someone directly about our services as a Sodium Molybdate Supplier, please call us on +44 (0)20 7183 0651 or visit our contact page, or contact us via LinkedIn and we will be happy to answer any of your questions.